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三羥丙烷的合成、用途以及使用注意

發(fā)布來源:http://www.shrisa.cn    更新時間:2023-02-14 點(diǎn)擊數(shù):57

三羥甲基丙烷(簡稱TMP),白色片狀結(jié)晶。易溶于水、低碳醇、甘油、N,N-二甲基甲酰胺,部分溶于丙酮、乙酸乙酯,微溶于四氯化碳、乙醚和氯仿。主要用于醇酸樹脂、聚氨酯、不飽和樹脂、聚酯樹脂、涂料等領(lǐng)域,也可用于合成航空潤滑油、印刷油墨等,還可用作紡織助劑和聚氯乙烯樹脂的熱穩(wěn)定劑。
Trimethylolpropane (TMP), white flake crystal. Easily soluble in water, lower alcohol, glycerin, N, N-dimethylformamide, partially soluble in acetone and ethyl acetate, slightly soluble in carbon tetrachloride, ether and chloroform. It is mainly used in alkyd resin, polyurethane, unsaturated resin, polyester resin, coating and other fields. It can also be used to synthesize aviation lubricating oil, printing ink, etc. It can also be used as textile auxiliaries and heat stabilizer of PVC resin.
合成方法
synthetic method 
正丁醛與甲醛在堿性性條件下進(jìn)行縮合反應(yīng),反應(yīng)液經(jīng)濃縮除鹽,再用離子交換樹脂脫色,提純,后用薄膜蒸發(fā)器蒸發(fā)、冷卻、軋片,得成品。
The condensation reaction of n-butyraldehyde and formaldehyde is carried out under alkaline conditions. The reaction solution is concentrated and desalted, then decolored and purified with ion exchange resin, and then evaporated, cooled and rolled with a film evaporator to obtain the finished product.
主要用途
Main purpose
三羥甲基丙烷是一種重要的精細(xì)化工產(chǎn)品,它是樹脂行業(yè)常用的擴(kuò)鏈劑。其熔點(diǎn)低,分子結(jié)構(gòu)中有3個羥甲基,可與有機(jī)酸反應(yīng)生成單酯或多酯,與醛、酮反應(yīng)生成縮醛、縮酮,與二異氰酸酯反應(yīng)生成氨基甲酸酯等。
Trimethylolpropane is an important fine chemical product. It is a chain extender commonly used in the resin industry. It has a low melting point and three hydroxymethyl groups in its molecular structure. It can react with organic acids to form monoesters or polyesters, react with aldehydes and ketones to form acetals and ketals, and react with diisocyanates to form carbamates.
三羥甲基丙烷
產(chǎn)品主要用于醇酸樹脂、聚氨酯、不飽和樹脂、聚酯樹脂、涂料等領(lǐng)域,也可用于合成航空潤滑油、增塑劑、表面活性劑、潤濕劑、炸藥、印刷油墨等,還可用作紡織助劑和聚氯乙烯樹脂的熱穩(wěn)定劑。
The products are mainly used in alkyd resin, polyurethane, unsaturated resin, polyester resin, coating and other fields, and can also be used to synthesize aviation lubricating oil, plasticizer, surfactant, wetting agent, explosive, printing ink, etc., and can also be used as textile auxiliaries and thermal stabilizer of PVC resin.
應(yīng)急處理
Emergency Management
隔離泄漏污染區(qū),限制出入。切斷火源。建議應(yīng)急處理人員戴防塵面具,穿一般作業(yè)工作服。用砂土、干燥石灰或蘇打灰混合。收集于干燥、潔凈、有蓋的容器中,轉(zhuǎn)移場所。若大量泄漏,收集回收或運(yùn)廢物處理場所處置。
Isolate the contaminated area and restrict access. Cut off the ignition source. It is recommended that emergency personnel wear dust masks and general work clothes. Mix with sand, dry lime or soda ash. Collect in a dry, clean and covered container and transfer to a safe place. If there is a large amount of leakage, it shall be collected and recycled or transported to the waste treatment site for disposal.
儲運(yùn)特性
Storage and transportation characteristics
1.操作注意事項(xiàng)。密閉操作,加強(qiáng)通風(fēng)。操作人員須經(jīng)過專門培訓(xùn),嚴(yán)格遵守操作規(guī)程。建議操作人員佩戴自吸過濾式防塵口罩。遠(yuǎn)離火種、熱源,工作場所嚴(yán)禁吸煙。使用防爆型的通風(fēng)系統(tǒng)和設(shè)備。避免與氧化劑、酸類接觸。搬運(yùn)時輕裝輕卸,防止包裝破損。配備相應(yīng)品種和數(shù)量的消防器材及泄漏應(yīng)急處理設(shè)備。倒空的容器可能殘留有害物。
1. Precautions for operation. Close operation and strengthen ventilation. Operators must receive special training and strictly abide by the operating procedures. It is recommended that operators wear self-priming filter dust masks. Keep away from kindling and heat sources. Smoking is strictly prohibited in the workplace. Use explosion-proof ventilation system and equipment. Avoid contact with oxidants and acids. Handle with care to prevent package damage. Provide fire fighting equipment and leakage emergency treatment equipment of corresponding types and quantities. Empty containers may contain harmful substances.
2.儲存注意事項(xiàng)。儲存于陰涼、通風(fēng)的庫房。遠(yuǎn)離火種、熱源。應(yīng)與氧化劑、酸類分開存放,切忌混儲。配備相應(yīng)品種和數(shù)量的消防器材。儲區(qū)應(yīng)備有合適的材料收容泄漏物。
2. Precautions for storage. Store in a cool and ventilated warehouse. Keep away from kindling and heat sources. It shall be stored separately from oxidants and acids, and mixed storage is prohibited. Provide fire fighting equipment of corresponding types and quantities. The storage area shall be equipped with appropriate materials to contain the leakage.
起運(yùn)時包裝要完整,裝載應(yīng)穩(wěn)妥。運(yùn)輸過程中要確保容器不泄漏、不倒塌、不墜落、不損壞。嚴(yán)禁與氧化劑、酸類等混裝混運(yùn)。運(yùn)輸途中應(yīng)防曝曬、雨淋,防高溫。更多相關(guān)產(chǎn)品的信息就來我們網(wǎng)站http://www.shrisa.cn咨詢吧!
The package shall be complete and the loading shall be stable when shipping. During transportation, ensure that the container does not leak, collapse, fall or damage. It is forbidden to mix and transport with oxidants, acids, etc. During transportation, it shall be protected from sunshine, rain and high temperature. For more information about related products, please visit our website http://www.shrisa.cn Ask!

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